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    [有機廢氣] 有機廢氣治理方法匯總

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    3373843實名認證 發表于 2011-8-31 17:59:16 | 只看該作者 |只看大圖 |閱讀模式 打印 上一主題 下一主題
    有機廢氣治理是指用多種技術措施,通過不同途徑減少石油損耗、減少有機溶劑用量或排氣凈化以消除有機廢氣污染。有機廢氣污染源分布廣泛。為防止污染,除減少石油損耗、減少有機溶劑用量以減少有機廢氣的產生和排放外,排氣凈化是目前切實可行的治理途徑。常用的方法有吸附法、吸收法、催化燃燒法、熱力燃燒法等。選用凈化方法時,應根據具體情況由縣選用費用低、耗能少、無二次污染的方法,盡量做到化害為利,充分回收利用成分和余熱。多數情況下,石油化工業因排氣濃度高,采用冷凝、吸收、直接燃燒等方法;涂料施工、印刷等行業因排氣濃度低,采用吸附、催化燃燒等方法。
    治理方法
    1、冷凝回收法:把有機廢氣直接導入冷凝器經吸附、吸收、解板、分離,可回收有價值的有機物,該法適用于有機廢氣濃度高、溫度低、風量小的工況,需要附屬冷凍設備,主要應用于制藥、化工行業,印刷企業較少采用。
    2、吸收法:一般采用物理吸收,即將廢氣引入吸收液進凈化,待吸收液飽和后經加熱、解析、冷凝回收;本法適用于大氣量、低溫度、低濃度的廢氣,但需配備加熱解析回收裝置,設備體積大、投資較高。
    一般采用活性炭吸附法 : 通過活性炭吸附廢氣,當吸附飽和后,活性炭脫附再生,將廢氣吹脫后催化燃燒,轉化為無害物質,再生后的活性炭繼續使用。當活性炭再生到一定次數后,吸附容量明顯下降,則需要再生或更新活性炭。
    活性炭是目前處理有機廢氣使用最多的方法,對苯類廢氣具有良好的吸附性能,但對烴類廢氣吸附性較差。主要缺點是運行成本較高,不適合于濕度大的環境。
    3、直接燃燒法:利用燃氣或燃油等輔助燃料燃燒,將混合氣體加熱,使有害物質在高溫作用下分解為無害物質;本法工藝簡單、投資小,適用于高濃度、小風量的廢氣,但對安全技術、操作要求較高。
    4、催化燃燒法:把廢氣加熱經催化燃燒轉化成無害無臭的二氧化碳和水;本法起燃溫度低、節能、凈化率高、操作方便、占地面積少、投資投資較大,適用于高溫或高濃度的有機廢氣。
    5、吸附法
    (1)直接吸附法:有機廢氣經活性炭吸附,可達95%以上的凈化率,設備簡單、投資小,但活性炭更換頻繁,增加了裝卸、運輸、更換等工作程序,導致運行費用增加。
    (2)吸附-回收法:利用纖維活性炭吸附有機廢氣,在接近飽和后用過熱水蒸汽反吹,進行脫附再生;本法要求提供必要的蒸汽量。
    (3)新型吸附-催化燃燒法:此法綜合了吸附法及催化燃燒法的優點,采用新型吸附材料(蜂窩狀活性炭)吸附,在接近飲和后引入熱空氣進行脫附、解析,脫附后廢氣引入催化燃燒床無焰燃燒,將其徹底凈化,熱氣體在系統中循環使用,大大降低能耗。本法具有運行穩定可靠、投資省、運行成本低、維修方便等特點,適用于大風量、低濃度的廢氣治理,是目前國內治理有機廢氣較成熟、實用的方法。

    活性碳纖維有機廢氣凈化回收裝置以活性碳纖維為吸附材料,可以高品質地從有機廢氣中回收烷烴、烯烴、芳香烴、酮、醇、醛、鹵代烴等有機溶劑和氣體,廢氣中有機物的回收率達99%以上,具有活性碳纖維用量少,裝置占地小,全自動運行,吸附解吸速度快,運轉耗能低,投資回收期短,環境效益顯著等一系列優點。

                               

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